Skip to main content

Brown Invitational — Forensics

Forensics · Division C · Brown Invitational · 2023

62 questions · 82 points · 50 min· 15 questions from the original omitted

Original test source
Figure

Materials: i. iodine reagent (I₂ dissolved in KI solution) ii. 2M HCl iii. 2M NaOH iv. Benedict's solution v. a hot water bath vi. a Bunsen burner or equivalent BTU heat source to perform flame tests vii. a waste container viii. chromatography materials (e.g., beakers, Petri dishes, etc.) ix. a wash bottle with distilled water

Possible Story Ideas: Hey! It's not a wonderful day. Arthur attended a party hosted by Buster last Saturday night, where he took off his glasses to play pin the tail on the anteater. When he finished his turn, he found his glasses snapped in two with blood residue on the broken lens. Buster, Francine, Muffy, Binky, DW, and Mr. Ratburn attended the party and denied breaking the glasses, refusing to pay for replacements. After careful examination of the glasses, it is known that spots of type O+ blood and pieces of fiber 4 and horse hair were found on the glasses, traces of a white powder 6 were found on the frames, and the culprit left a tented arch-type fingerprint on the frame! Below are the fellow suspects present at the party that day and a recording of their confessions to what they were doing that night:

Buster: Buster was the host of the party. He was wearing a cotton tee shirt and seen eating salt and vinegar chips. He picked up a pony earlier that night just for the party. Francine: Francine was dancing all night at the party. Some kind of weak acid used for fireproofing was found on her cup. Furthermore, because she has a pet squirrel, traces of squirrel hairs were found on her linen shirt. Muffy: Muffy was sleeping on a linen couch during the party. She was seen going to the bathroom to brush her teeth after she got a popcorn kernel stuck during the party. Binky: Binky said he was in the bathroom when Aurthur went around screaming his glasses were broken to take his medicine for his diagnosed bipolar disorder. Pieces of polyesters were found in Binky's tie. DW: DW was in the kitchen all night during the party. She baked a cake right before the party and still had traces of cake mix on hh Mr. Ratburn: Mr. Ratburn said he was busy correcting homework assignments all night at the party. However, it is known that he took calcium supplements and was wearing wool pants that night. His pet bat came with him to party that night and was by his side all night.

Structure of Test/Point Distribution:

  1. Scenario
  2. Suspects
  3. Powders Identification
  4. Fibers
  5. Hair
  6. Plastics
  7. Chromatography
  8. Mass Spectroscopy
  9. Fingerprints
  10. Blood
  11. Final Analysis

Powders Direction :: Identify the powders according to the number on the bag (#1-6) then answer the multiple choice questions below (#7-17)

Question 5

2 pts

Powder 5 is insoluble in water, has a reaction to HCl, and pH of 8. What is Powder 5?

Question 7

2 pts

To test for pH, usually litmus paper is used. Litmus is extracted from which plant?

Question 8

2 pts

Another method of testing pH is using phenolphthalein. If a solution turns pink in phenolphthalein, what kind of solution is it?

Question 9

2 pts

Which of the following powders is the least soluble in distilled water?

Question 10

2 pts

Which of the following powders has an endothermic heat of solution?

Question 11

2 pts

Complete the chemical reaction between sodium bicarbonate and hydrochloric acid: NaHCO₃(aq) + HCl(aq) →

Question 12

2 pts

Complete the chemical reaction between calcium nitrate and sodium hydroxide: Ca(NO₃)₂(aq) + 2NaOH(aq) →

Question 13

2 pts

The iodine used in iodine testing isn't pure iodine; it is called Lugol's iodine. What is iodine mixed with in water to produce Lugol's iodine?

Question 14

2 pts

A solution turns green when it reacts with Benedict's solution. What does this solution likely contain?

Question 15

2 pts

Which of the following powders has a red flame in a flame test?

Question 16

2 pts

A flame test is done on a powder, and it results in a yellow flame. However, when cobalt blue glass is used, a violet flame can be seen. What powder is being tested?

Question 17

2 pts

What color light does cobalt blue glass absorb?

Fibers Directions :: Identify the following fibers (#1-5) and answer the accompanying questions (#6-10)

Question 5

1 pt

What is Fiber 5?

Question 6

1 pt

Which of the following fibers can be dissolved in 6M hydrochloric acid?

Question 7

1 pt

Which of the following fibers can be dissolved in bleach?

Question 8

1 pt

A burn test is done on a fiber. The fiber slowly melts, and a black sticky substance remains. Which fiber is this?

Question 9

1 pt

What shape is silk's cross section under a microscope?

Hair Directions :: Identify the following hair (#1-5) and answer the accompanying questions (#6-12)

FigureFor questions 1–5

Hair samples: A B C D

Question 1

1 pt

What kind of hair is in box A?

Question 2

1 pt

What kind of hair is in box B?

Question 3

1 pt

What kind of hair is in box C?

Question 4

1 pt

What kind of hair is in box D?

Question 5

1 pt

The hair in box B was found in the blood on the glasses. Who does this implicate?

Question 6

1 pt

Which of the following stages of hair growth describes the active growing stage?

Question 7

1 pt

Which of the following stages of hair growth describes the transitional stage between actively growing and resting?

Question 8

1 pt

Which of the following stages of hair growth describes the resting stage?

Question 9

1 pt

Which of the following stages of hair growth describes the shedding stage?

Question 10

1 pt

Which of the following stages of hair growth describes the stage between an empty hair follicle and a new hair?

Question 11

1 pt

The hair consists of a cuticle, medulla, and cortex. If you were to name each component in order from the outer edge of a hair to its inner core, what would it be the order that each component is named?

Question 12

1 pt

The biggest way to differentiate animal and human hair is the difference in their medullary index. Which of the following medullary indices is likely to be that of a human hair?

Plastics Directions : Answer the following questions (#1-10) about plastics below

Question 1

1 pt

Which of the following would burn green?

Question 2

1 pt

A type of plastic that would be used to make a Walmart plastic bag is:

Question 3

1 pt

What is the most common type of plastic in the world?

Question 4

1 pt

You found a really sick pair of sunglasses on the ground. What type of plastic is it made of?

Question 5

1 pt

What happens when you react with polystyrene with acetone?

Question 6

1 pt

What is the density of Polyvinyl Chloride?

Question 7

1 pt

Identify the following structure below:

Question 9

1 pt

Which type of structure is easier to recycle?

Question 10

1 pt

Why is the other structure harder to recycle?

MASS SPECTROMETRY

FigureFor questions 1–2

Use the following mass spectrometry of an unknown substance collected from Arthur's sweater to complete questions 1-2.

Question 1

5 pts

What is the base peak of the compound?

Question 2

5 pts

What is the molecular formula for this compound?

Blood Direction: Answer the following questions (#1-15) below

FigureFor questions 1–4

DIRECTIONS: Use the table below to answer #1-4

Microscope Slide AMicroscope Slide BMicroscope Slide C

Question 1

1 pt

Identify which group of animal Microscope Slide A belongs to:

Question 2

1 pt

Identify which group of animal Microscope Slide B belongs to:

Question 3

1 pt

Identify which group of animal Microscope Slide C belongs to:

Question 4

1 pt

Which microscope slide is closest to Arthur's blood sample?

FigureFor questions 5–12

DIRECTIONS: Blood samples were taken for the following animals. Identify what blood type they are using the information given:

SuspectBusterFrancineMuffyBinkyDWMr. Ratburn

Question 5

1 pt

What blood type is Buster?

Question 6

1 pt

What blood type is Francine?

Question 7

1 pt

What blood type is Muffy?

Question 8

1 pt

What blood type is Binky?

Question 9

1 pt

What blood type is DW?

Question 10

1 pt

What blood type is Mr. Ratburn?

Question 11

1 pt

If Francine is what is known as a universal donor, what blood type is he?

Question 12

1 pt

Who has the rarest blood type?

PassageFor question 15

DIRECTIONS: Below are some conceptual questions about blood type:

Question 15

1 pt

What is a Rh factor?

Fingerprint Direction: Answer the following questions (#16-24) about fingerprints, use the diagrams as needed

FigureFor questions 16–21

Fingerprints: 1. Buster, 2. Francine, 3. Muffy, 4. Binky, 5. DW, 6. Mr. Ratburn

Question 16

1 pt

What type of fingerprint is fingerprint 1?

Question 17

1 pt

What type of fingerprint is fingerprint 2?

Question 18

1 pt

What type of fingerprint is fingerprint 3?

Question 19

1 pt

What type of fingerprint is fingerprint 4?

Question 20

1 pt

What type of fingerprint is fingerprint 5?

Question 21

1 pt

What type of fingerprint is fingerprint 6?

Question 22

1 pt

This fingerprint was collected from Arthur's shattered glasses. Who does it implicate?

Question 23

1 pt

What ridge characteristic is circled in the fingerprint in the previous question?

Question 24

1 pt

What type of fingerprint development methods would be used to examine latent fingerprints on a paper cup?